Thursday, 16 August 2001, 11:00
am
Link Building Seminar Room
Dr David Williams
Dept. of Applied Mathematics
Particle Interactions in Biology
and Soft Matter:
Why Onsager and Landau are wrong
ABSTRACT:
Colloid "science" should underly
a great many important systems from biology to minerals extraction.
However, it has not contributed as it should.
The reason is that the theory which underlies much of colloid science
is inadequate, and in many cases incorrect. In particular, ubiquitous
specific ion effects are not accounted for by traditional theories,
and the traditional theories have almost no predictive value.
In this talk I will outline the defects of two current theories. These
are
(i) The Onsager-Samaris theory of the surface tension of salt solutions
(ii) The Deryaguin-Landau-Verwey-Overbeek (DLVO) theory of colloidal
interactions.
It will be shown how the current theories fail for biological systems
and how these theories can be corrected by proper inclusion of all the
forces acting on the particles.
Ref: Bostrom, Williams, Ninham: Langmuir (in press).
Bostrom, Williams, Ninham: PRL (to appear)